Physicochemical Characterization of Calliandra surinamensis Seed Oil
Keywords:
Calliandra Surinamensis Seeds, oil, Physicochemical, Soxhlet Extraction, CharacterizationAbstract
Calliandra surinamensis seed oil is a promising non-traditional oilseed crop with potential food, cosmetic, and pharmaceutical applications. The oil from Calliandra surinamensis seeds was extracted using the Soxhlet extraction method with hexane as the solvent. The chemical characterisation showed that C. surinamensis oil registered a saponification index of 158.95 mg KOH/g oil, an Iodine index of 101.14 g 1/100 g oil, a peroxide index of 7.27 meg O2/kg, an acid index of 10.94 mg KOH/g oil, and a free fatty acid index of 5.47 mg/g. The physical characteristics revealed that C. surinamensis oil has a refraction index (25) of, 1.2667, a specific gravity of 0.8973, a smoke point (oC) of 111.67, a flash point (oC) of 228.33, a fire point (oC) of above 300, a pH of 6.27, a viscosity of 5.80 and a yellow colour. The sample oil showed a moderate saponification index, suggesting a balanced fatty acid composition and good oxidative stability due to its relatively low peroxide value.
References
Akpan, U. G., Jimoh, A., & Mohammed, A. D. (2006). Extraction, characterization, and modification of castor seed oil. Leonardo Journal of Sciences, 8, 43-52.
Akubugwo, I. E., Chinyere, G. C., & Ugbogu, A. E. (2008). Industrial qualities of rubber seed oils. Nigerian Journal of Technical Research, 11(1-2), 1-2.
Akubugwo, I. E., Obasi, N. A., Chinyere, G. C., & Ugbogu, A. E. (2007). Nutritional and chemical value of Amaranthus hybridus L. leaves from Afikpo, Nigeria. African Journal of Biotechnology, 6(24), 2833-2839.
Ameh, V. I., Ayeleru, O. O., Nomngongo, P. N., & Ramatsa, I. M. (2024). Bio-oil production from waste plant seeds biomass as pyrolytic lignocellulosic feedstock and its improvement for energy potential. Waste Management Bulletin, 2(2), 32-48.
Association of Official Analytical Chemists (AOAC). (2005). Official methods of analysis (20th ed.). Washington, DC: Author. Codex Alimentarius Commission. (2007). Codex alimentarius: cereals, pulses, legumes, and vegetable proteins. Rome: World Health Organization: Food and Agriculture Organization of the United Nations.
Cornelio-Santiago, H. P., Bodini, R. B., & Oliveira, A. L. (2021). Potential of oilseeds native to Amazon and Brazilian Cerrado biomes: Benefits, chemical and functional properties, and extraction methods. Journal of the American Oil Chemists’ Society, 98(1), 3-20.
Dhellot, J. R., Matuoba, E., Maloumbi, M. G., Nzikou, J. M., & Dzondo, M. G. S. (2006). Extraction and nutritional properties of Solanum nigum L. seed oil. African Journal of Biotechnology, 5(11), 987-991.
Ettefaghi, E., Ahmadi, H., Rashidi, A., Mohtasebi, S. S., & Alaei, M. (2013). Experimental evaluation of engine oil properties containing copper oxide nanoparticles as nanoadditive. International Journal of Industrial Chemistry, 4(1), 1-9.
Eze, P. N., Obielumani, J. O., & Okotcha, E. N. (2022). Extraction of oil and fatty acid composition of Calliandra surinamensis seed. Journal of Research in Science and Technical Education (JOREST), 4(1).
Ichu, C. B., & Nwakanma, H. O. (2019). Comparative study of physicochemical characterization and quality of edible vegetable oils. International Journal of Research in Informative Science Application and Techniques (IJRISAT), 11.
Ikhuoria, A. E., Aiwonegbe, A., & Okoli, P. (2006). Characterization and composition of African oil bean seed (Pentaclethra macrophylla benth). ChemTech Journal, 2, 309-312.
Ikhuoria, M., Aibaugbe, A., & Maliki, M. (2006). Extraction and characterization of avocado pear (Persea americana) and African pear (Dacryodes edulis). ChemTech Journal, 2, 345-349.
Irabor, E. E. I., Eze P. N., Unuigbe, C. A., Imafidon, M. I., Omoruyi, U. & Emmanuel. V. (2023).’Proximate analysis and Mineral Determination of Calliandra surinamensis seed’. Journal of chemical society of Nigeria, Vol. 48, No. 1, pp 183-191.
Kyari, M. Z. (2008). Extraction and characterization of seed oils. International Agrophysics, 22, 139-142.
Nangbes, J. G., Nvau, J. B., Buba, W. M., & Zukdimma, A. N. (2013). Extraction and characterization of castor (Ricinus communis) seed oil. International Journal of Engineering and Science (IJES), 2(9), 105-109.
Obasi, N. A., Ukadilonu, J., Eze, E., Akubugwo, E. I., & Okorie, U. C. (2012). Extraction, characterization, and comparative assessment of coconut (Cocos nucifera) and melon (Colocynthis citrullus) seed. Pakistan Journal of Biological Sciences, 15(1), 1-9.
Segura-Campos, M. R., Ciau-Solís, N., Rosado-Rubio, G., Chel-Guerrero, L., & Betancur-Ancona, D. (2014). Physicochemical characterization of chia (Salvia hispanica) seed oil from Yucatán, México. Agricultural Sciences, 5(3), 43020.
Turner, R. (2010). Fat and oils quality characteristics, extraction, and refining overview. Farm Energy Conference, Manchester. International Journal of Engineering and Science (IJES). www.uvm.edu/extension/cropsoil/wp-
Yara-Varón, E., Li, Y., Balcells, M., Canela-Garayoa, R., Fabiano-Tixier, A. S., & Chemat, F. (2017). Vegetable oils as alternative solvents for green oleo-extraction, purification and formulation of food and natural products. Molecules, 22(9), 1474.
Yusuf, A. A., Adewuyi, S., & Lasisi, A. A. (2006). Physicochemical composition of leaves, meals, and oil of fluted pumpkin (Telfairia occidentalis) and melon (Citrullus vulgaris).